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I feel like Shocker is gonna be the first to be attacked, though also being a formidable foe. Keep in mind that this is just a regular dude with gauntlets that let out shock waves, unlike most of Spider-Mans pther villains that either have super powers, years of training or something like a power suit or super drug. He's just a normal dude with a couple of gadgets and somehow he can fight someone as strong as Spider-Man, I think he can last a while against Batman. Especially with someone like Scorpian by his side.